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716782

Sigma-Aldrich

N-((Diisopropylamino)methylene)-N-diisopropylaminium tetrafluoroborate

97%

Synonym(s):

N,N,N′,N′-Tetraisopropylformamidinium tetrafluoroborate, Bis-(Diisopropylamino)methylium tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):
C13H29BF4N2
CAS Number:
369405-27-6
Molecular Weight:
300.19
MDL number:
MFCD15144860
UNSPSC Code:
12352001
PubChem Substance ID:
329763428
NACRES:
NA.22

assay

97%

form

solid

reaction suitability

reagent type: catalyst

mp

280-284 °C

SMILES string

F[B-](F)(F)F.CC(C)N(\C=[N+](\C(C)C)C(C)C)C(C)C

InChI

1S/C13H29N2.BF4/c1-10(2)14(11(3)4)9-15(12(5)6)13(7)8;2-1(3,4)5/h9-13H,1-8H3;/q+1;-1

InChI key

PEKVUVXZBLFOHV-UHFFFAOYSA-N

application

Reactant for cross-coupling reactions

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Bhartesh Dhudshia et al.
Chemical communications (Cambridge, England), 6(6), 668-670 (2006-02-01)
Acyclic diaminocarbenes are found to be useful ligands for palladium catalyzed Suzuki-Miyaura, Sonogashira and Heck cross-coupling reactions of aryl/alkenyl bromides and chlorides.

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