707988
Grubbs Catalyst® C859
95%
Synonym(s):
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate, Piers second generation metathesis catalyst, [SIMes]dichloro[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate
About This Item
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Quality Level
assay
95%
form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization
mp
176 °C (dec.)
storage temp.
2-8°C
SMILES string
F[B-](F)(F)F.Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=C[P+](C4CCCCC4)(C5CCCCC5)C6CCCCC6)c(C)c1
InChI
1S/C21H26N2.C19H34P.BF4.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;2-1(3,4)5;;;/h9-12H,7-8H2,1-6H3;1,17-19H,2-16H2;;2*1H;/q;+1;-1;;;+2/p-2
InChI key
KMTPXIJXNIAPCS-UHFFFAOYSA-L
Application
Legal Information
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Articles
Alkyne metathesis has been a useful tool for C–C bond formation since the discovery of structurally well-defined metal alkylidynes by Schrock and coworkers.
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Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.
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