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701610

Sigma-Aldrich

Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate

97%

Synonym(s):

Bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]rhodium 1,1,1-trifluoromethanesulfonate

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About This Item

Empirical Formula (Hill Notation):
C15H16F3O3RhS
CAS Number:
178397-71-2
Molecular Weight:
436.25
UNSPSC Code:
12161600
PubChem Substance ID:
329762309
NACRES:
NA.22

assay

97%

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

mp

119-121 °C

storage temp.

−20°C

SMILES string

[Rh+].C1C2C=CC1C=C2.C3C4C=CC3C=C4.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/2C7H8.CHF3O3S.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)8(5,6)7;/h2*1-4,6-7H,5H2;(H,5,6,7);/q;;;+1/p-1

InChI key

ZSVUXIMOLSTJPA-UHFFFAOYSA-M

Application

Reactant for:
  • Metalation via C-C bond cleavage
  • Synthesis of rhodium/ph-binepine catalysts

Catalyst for enantioselective hydrogenation

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
90797KJ

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