Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

View All Documentation

701475

Sigma-Aldrich

Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV)

Synonym(s):

Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV), Dichloro-2,6,10-dodecatrienylene-ruthenium, Dichloro[(1,2,3,6,7,10,11,12-η)-2,6,10-dodecatriene-1,12-diyl]-ruthenium

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C12H18Cl2Ru
CAS Number:
12170-97-7
Molecular Weight:
334.25
MDL number:
MFCD08459354
UNSPSC Code:
12161600
PubChem Substance ID:
329762293
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

core: ruthenium
reagent type: catalyst

mp

190 °C

SMILES string

Cl[Ru]1(Cl)C\C=C\CCC=CCC\C=C\C1

InChI

1S/C12H18.2ClH.Ru/c1-3-5-7-9-11-12-10-8-6-4-2;;;/h3-6,11-12H,1-2,7-10H2;2*1H;/q;;;+2/p-2/b5-3+,6-4+,12-11-;;;

InChI key

RSRAKQPWMXANGM-LXALEWKWSA-L

Application

Catalyst for:
  • Redox isomerization/transfer hydrogenation
  • Deprotection of N-allyl amides and lactams
  • Isomerization of allylamines
  • Isomerization of allylic alcohols into carbonyl compounds
Catalysts used in the deprotection of N-allyl amides and lactams

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKBB3513
MKBC5625

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Cadierno, V. et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 6590-6590 (2007)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service