695181

Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium

• Empirical Formula (Hill Notation): C₅₉H₄₉F₁₈O₄P₂Rh
• CAS Number: 851530-57-9
• Molecular Weight: 1328.84
• MDL number: MFCD10567050
• UNSPSC Code: 12352300
• PubChem Substance ID: 329761724

Properties

• form: powder
• reaction suitability: core: rhodium; reagent type: catalyst
• mp: 204-206 °C
• SMILES string: Cc1ccc(cc1)[Rh](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C.FC(F)(F)c2ccc(cc2)P(c3ccc(cc3)C(F)(F)F)c4ccc(cc4)C(F)(F)F.FC(F)(F)c5ccc(cc5)P(c6ccc(cc6)C(F)(F)F)c7ccc(cc7)C(F)(F)F
• InChI: 1S/2C21H12F9P.C7H7.2C5H10O2.Rh/c2*22-19(23,24)13-1-7-16(8-2-13)31(17-9-3-14(4-10-17)20(25,26)27)18-11-5-15(6-12-18)21(28,29)30;1-7-5-3-2-4-6-7;2*1-5(2,3)4(6)7;/h2*1-12H;3-6H,1H3;2*1-3H3,(H,6,7);/q;;;;;+2/p-2
• InChI key: XAQKQHIYPBKBNW-UHFFFAOYSA-L

Description

General description

Extremely selective C-arylation catalyst for unprotected indoles and pyrrolidines

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable