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692239

Sigma-Aldrich

(R)-Ru(OAc)2(T-BINAP)

Synonym(s):

Diacetato[(R)-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C52H46O4P2Ru
CAS Number:
116128-29-1
Molecular Weight:
897.94
MDL number:
MFCD09753021
UNSPSC Code:
12352005
PubChem Substance ID:
329761477
NACRES:
NA.22

form

powder

Quality Level

100

functional group

phosphine

storage temp.

2-8°C

SMILES string

CC(=O)O[Ru]OC(C)=O.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8

InChI

1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;2*1-2(3)4;/h5-32H,1-4H3;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

HXHQOYKBZFDKSM-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR9076
MKBG9189
07326HJ
04125LH

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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