676667
B-Methoxy-10-trimethylsilyl-9-borabicyclo(3.3.2)decane
95%
Synonym(s):
10-TMS-9-BBD, 10-TMS-9-Borabicyclo[3.3.2]decane, 9-Methoxy-10-trimethylsilanyl-9-borabicyclo(3.3.2)decane
About This Item
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assay
95%
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.494
bp
85 °C/0.4 mmHg
density
0.934 g/mL at 25 °C
SMILES string
COB1C2CCCC(CCC2)C1[Si](C)(C)C
InChI
1S/C13H27BOSi/c1-15-14-12-9-5-7-11(8-6-10-12)13(14)16(2,3)4/h11-13H,5-10H2,1-4H3
InChI key
AUJACFLHZMIAEG-UHFFFAOYSA-N
Application
Reactant for:
- Palladium-catalyzed allylation reaction
- Hydroboration of allenes
- Stereoselective γ-methoxyallylation reactions
- Asymmetric carboborylation reactions
- Insertion and borotropic rearrangement reactions
- Asymmetric Michael addition reactions
- Asymmetric propargylation of aldehydes
- Asymmetric allenylboration reactions
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Liq. 3 - Water-react 2
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 3
flash_point_f
138.9 °F - closed cup
flash_point_c
59.4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
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