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672599

Sigma-Aldrich

(R)-(+)-1-(2,4,6-Triisopropylphenyl)ethanol

≥96.0% (HPLC)

Synonym(s):

(R)-Stericol®

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About This Item

Empirical Formula (Hill Notation):
C17H28O
CAS Number:
181531-14-6
Molecular Weight:
248.40
MDL number:
MFCD09836214
UNSPSC Code:
12352002
PubChem Substance ID:
329760516
NACRES:
NA.22
assay:
≥96.0% (HPLC)

assay

≥96.0% (HPLC)

optical purity

enantiomeric ratio: ≥98:2 (HPLC)

functional group

hydroxyl

storage temp.

2-8°C

SMILES string

CC(C)c1cc(C(C)C)c([C@@H](C)O)c(c1)C(C)C

InChI

1S/C17H28O/c1-10(2)14-8-15(11(3)4)17(13(7)18)16(9-14)12(5)6/h8-13,18H,1-7H3/t13-/m1/s1

InChI key

VYKPQIIFUMKNLF-CYBMUJFWSA-N

application

R(+) & S(-) Stericol Chiral Auxiliaries

Legal Information

Stericol is a registered trademark of Université Joseph Fourier

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
1329849V
1329849

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A New Asymmetric Carbon-Carbon Bond Forming Reaction: Four-Component Stereoselective Synthesis of (Z)-4,6-Dihydroxy-3-methylalk-2-enyl Methyl Sulfones This work was supported by the Swiss National Science Foundation.
Narkevitch et al.
Angewandte Chemie (International ed. in English), 39(10), 1806-1808 (2000-08-10)
Caroline Roche et al.
The Journal of organic chemistry, 70(21), 8352-8363 (2005-10-08)
Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomerically enriched form through a highly selective [2 + 2]-cycloaddition of dichloroketene with a chiral
Hamel, M., et al.
Tetrahedron Asymmetry, 16, 3406-3415 (2005)

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