670650

(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine

97%

• Synonym(s): (1R)-trans-N-Boc-1,2-diaminocyclohexane
• Empirical Formula (Hill Notation): C₁₁H₂₂N₂O₂
• CAS Number: 146504-07-6
• Molecular Weight: 214.30
• Beilstein/REAXYS Number: 7023564
• MDL number: MFCD08726023
• UNSPSC Code: 12352108
• PubChem Substance ID: 329760379
• NACRES: NA.22

Properties

• assay: ≥96.5%; 97%
• form: solid
• optical activity: [α]/D -26±2°, c = 1 in chloroform
• optical purity: ee: ≥99.0%
• functional group: amine
• SMILES string: CC(C)(C)OC(=O)N[C@@H]1CCCC[C@H]1N
• InChI: 1S/C11H22N2O2/c1-11(2,3)15-10(14)13-9-7-5-4-6-8(9)12/h8-9H,4-7,12H2,1-3H3,(H,13,14)/t8-,9-/m1/s1
• InChI key: AKVIZYGPJIWKOS-RKDXNWHRSA-N

Description

Application

(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:

• An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
• A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges