Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

669660

Sigma-Aldrich

(S,S)-(+)-N,N′-Dimethyl-1,2-cyclohexanediamine

≥97.0% (GC)

Synonym(s):

(1S)-trans-1,2-Bis(methylamino)cyclohexane, (S,S)-N,N′-Dimethyl-1,2-diaminocyclohexane

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C8H18N2
CAS Number:
Molecular Weight:
142.24
Beilstein/REAXYS Number:
4304824
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

assay

≥97.0% (GC)

optical activity

[α]/D +145±5°, c = 4.47 in chloroform

mp

39-44 °C

functional group

amine

storage temp.

2-8°C

SMILES string

CN[C@H]1CCCC[C@@H]1NC

InChI

1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m0/s1

InChI key

JRHPOFJADXHYBR-YUMQZZPRSA-N

application

(S,S)-(+)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:
  • To synthesize derivatives of α-diazophosphonic acid, which are employed in O-H and N-H insertion reactions.[1]
  • As a starting material for the synthesis of α-chloro-α-alkylphosphonic acids.[2]
  • To prepare C2 symmetrical diamine enantiomers of C60 with chirospectrosopic properties.[3]

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and characterization of both enantiomers of a chiral C60 derivative with C2 symmetry
Maggini M, et al.
Tetrahedron Letters, 36(16), 2845-2846 (1995)
(3a R, 7a R)-2-Ethyloctahydro-1 H-1, 3-dineopentyl-1, 3, 2-benzodiazaphosphole Oxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 12(11), 1657-1661 (2001)
Preparation of chiral α-diazophosphonic acid derivatives
Moody CJ, et al.
Tetrahedron Asymmetry, 12(11), 1657-1661 (2001)

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service