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667900

N-Boc-2-indolyldimethylsilanol

Name: <I>N</I>-Boc-2-indolyldimethylsilanol
Brand: ALDRICH

95%

Synonym(s):

2-(hydroxydimethylsilyl)-1,1-dimethylethylindole-1-carboxylic acid ester, N-Boc-indol-2-yldimethylsilanol

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About This Item

Linear Formula:

((C₈H₅N)(CO₂C(CH₃)₃))Si(CH₃)₂(OH)

CAS Number:

784161-48-4

Molecular Weight:

291.42

MDL number:

MFCD08457643

UNSPSC Code:

12352100

PubChem Substance ID:

24884947

NACRES:

NA.22

assay

95%

refractive index

n20/D 1.545

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=O)n1c(cc2ccccc12)[Si](C)(C)O

InChI

1S/C15H21NO3Si/c1-15(2,3)19-14(17)16-12-9-7-6-8-11(12)10-13(16)20(4,5)18/h6-10,18H,1-5H3

InChI key

ARJIKJGACIMUOM-UHFFFAOYSA-N

Application

Reactant for:
Palladium-catalyzed cross-coupling reactions

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Denmark, S. E.; Ober, M. H.

Aldrichimica Acta, 36, 75-75 (2003)

Articles

Organosilanols

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

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