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61196

Sigma-Aldrich

Copper(I) iodide trimethylphosphite complex

≥99.0% (RT)

Synonym(s):

Cuprous iodide trimethylphosphite complex

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About This Item

Linear Formula:
CuI · P(OCH3)3
CAS Number:
34836-53-8
Molecular Weight:
314.53
Beilstein/REAXYS Number:
3671063
EC Number:
252-237-6
MDL number:
MFCD00034815
UNSPSC Code:
12352300
PubChem Substance ID:
57651833

assay

≥99.0% (RT)

reaction suitability

reagent type: catalyst
core: copper

mp

192-193 °C (dec.)
192-193 °C (lit.)

SMILES string

[Cu]I.COP(OC)OC

InChI

1S/C3H9O3P.Cu.HI/c1-4-7(5-2)6-3;;/h1-3H3;;1H/q;+1;/p-1

Inchi Key

MXHFJMDNOFWFFV-UHFFFAOYSA-M

Other Notes

Preparation of copper enolates[1]; Alkylation of trimethylsilylvinyl aluminates.[2]

Pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
043156/1
43156/1
40107/1
040107/1

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F.E. Ziegler et al.
The Journal of Organic Chemistry, 46, 825-825 (1981)
F. Ziegler et al.
Tetrahedron Letters, 25, 131-131 (1984)

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