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594458

Sigma-Aldrich

4-Methoxyphenyl isocyanide

97%

Synonym(s):

1-Isocyano-4-methoxybenzene, 4-Isocyanoanisole, 4-Methoxy-1-isocyanobenzene, 4-Methoxyphenyl isonitrile, Anisyl isonitrile, p-Anisyl isocyanide, p-Anisyl isonitrile, p-Methoxyphenyl isocyanide, p-Methoxyphenyl isonitrile

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About This Item

Linear Formula:
H3COC6H4NC
CAS Number:
10349-38-9
Molecular Weight:
133.15
MDL number:
MFCD02664592
UNSPSC Code:
12352100
PubChem Substance ID:
24881510
NACRES:
NA.22

Quality Level

100

assay

97%

mp

29-33 °C (lit.)

storage temp.

−20°C

SMILES string

COc1ccc(cc1)[N+]#[C-]

InChI

1S/C8H7NO/c1-9-7-3-5-8(10-2)6-4-7/h3-6H,2H3

InChI key

MIEQKTRWKZYUPY-UHFFFAOYSA-N

Application

4-Methoxyphenyl isocyanide can be used to synthesize N-(isoquinolin-1-yl)-formamides via reaction with 2-alkynylbenzaldoximes in the presence of silver trifluoromethanesulfonate and bismuth triflate.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

224.6 °F - closed cup

flash_point_c

107 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL7747
BCCJ4604
BCCF8028
BCCB7123
BCBZ4514

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"Multicatalytic Tandem Reactions of 2-Alkynylbenzaldoximes with Isocyanides"
Chen Z, et al.
AZo Journal of Materials Online, 351(16), 2702- 2708 (2009)
Hideaki Komiyama et al.
Nanotechnology, 26(39), 395302-395302 (2015-09-12)
We present an alternative approach to fabricating hexagonally arranged nanodot arrays of various metals by seed-mediated electroless plating with a cylinder-forming block copolymer thin film, PEO-b-PMA(Az), as a scaffold. Metal ions were selectively incorporated into PEO cylinders, followed by their

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