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578789

Sigma-Aldrich

5,6-Epoxy-5,6-dihydro-[1,10]phenanthroline

98%

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About This Item

Empirical Formula (Hill Notation):
C12H8N2O
CAS Number:
65115-91-5
Molecular Weight:
196.20
MDL number:
MFCD02170901
UNSPSC Code:
12352100
PubChem Substance ID:
24880951
NACRES:
NA.22

assay

98%

form

solid

mp

183 °C (dec.) (lit.)

functional group

ether

SMILES string

O1C2C1c3cccnc3-c4ncccc24

InChI

1S/C12H8N2O/c1-3-7-9(13-5-1)10-8(4-2-6-14-10)12-11(7)15-12/h1-6,11-12H

InChI key

GGQHROHZSIPVQE-UHFFFAOYSA-N

Application

5,6-Epoxy-5,6-dihydro-[1,10]phenanthroline may be used to synthesize N-(3-azidopropyl)-1,10-phenanthrolin-5-amine (az-phen), via reaction with 3-azidopropylamine which is then subjected to dehydration by treatment with sodium hydride.[1] It can also be used to synthesize (1,10-phenanthrolin-5-yl)-1-thio-β-D-glucopyranoside by reacting with 1-thio-β-D-glucopyranose sodium salt in dry ethanol.[2]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCF6535
MKBT5876V
MKBP4335V
MKBK2322V
MKBG6910V

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Lucon J, et al
Chemical Communications (Cambridge, England), 46(02), 264- 266 (2010)

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