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578703

Sigma-Aldrich

Dichloro(3-methyl-2-butenylidene)bis(tricyclopentylphosphine)ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C35H62Cl2P2Ru
CAS Number:
220883-08-9
Molecular Weight:
716.79
MDL number:
MFCD04039971
UNSPSC Code:
12352300
PubChem Substance ID:
24880945

form

solid

mp

94-96 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(C1)P(C2CCCC2)C3CCCC3.C4CCC(C4)P(C5CCCC5)C6CCCC6

InChI

1S/2C15H27P.C5H8.2ClH.Ru/c2*1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;1-4-5(2)3;;;/h2*13-15H,1-12H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

InChI key

UCDVULRIJNJVEV-UHFFFAOYSA-L

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

  • Reactant for synthesis of ruthenium olefin metathesis catalysts

  • Catalyst for ring-opening metathesis polymerization
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.[1][2][3][4][5][6]

Other Notes

NO BULK ORDERS

Legal Information

US Patent No. 5,969,170 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For questions, please contact us at [email protected]

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
01729KH
15315JA

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Furstner, A.
Angewandte Chemie (International Edition in English), 3012-3012 (2000)
Schuster, M.; Blechert, S.
Angewandte Chemie (International Edition in English), 2036-2036 (1997)
Vougioukalakis, G. C.; Grubbs, R. H.
Chemical Reviews, 1746-1746 (2010)
Grubbs, R. H.
Tetrahedron, 7117-7117 (2004)
Trnka, T. M.; Grubbs, R. H.
Accounts of Chemical Research, 18-18 (2001)
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