569763

(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

97%

• Empirical Formula (Hill Notation): C₁₃H₁₈N₂O · HCl
• CAS Number: 278173-23-2
• Molecular Weight: 254.76
• MDL number: MFCD03426983
• UNSPSC Code: 12352005
• PubChem Substance ID: 24880521
• NACRES: NA.22

Properties

• assay: 97%
• form: solid
• optical activity: [α]20/D -67°, c = 1 in H₂O
• mp: 157-161 °C (lit.)
• functional group: phenyl
• SMILES string: Cl.CN1C(=O)[C@H](Cc2ccccc2)NC1(C)C
• InChI: 1S/C13H18N2O.ClH/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;/h4-8,11,14H,9H2,1-3H3;1H/t11-;/m0./s1
• InChI key: YIYFEXGDFJLJGM-MERQFXBCSA-N

Description

Application

Metal-free OrganoCatalyst technology for asymmetric catalysis. Catalyzes asymmetric Diels-Alder reactions, 1,3-dipolar additions and pyrrole alkylations in high enantiomeric excess.

Used in first highly enantioselective organocatalytic Diels-Alder reaction[1] and 1,3-dipolar addition.[2]

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)