562076

3,5-Dimethylphenylmagnesium bromide solution

0.5 M in THF

• Linear Formula: (CH₃)₂C₆H₃MgBr
• CAS Number: 34696-73-6
• Molecular Weight: 209.37
• MDL number: MFCD01311497
• UNSPSC Code: 12352103
• PubChem Substance ID: 24880004
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.950 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Cc1cc(C)cc([Mg]Br)c1
• InChI: 1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1
• InChI key: XPXQQJMQESWIKM-UHFFFAOYSA-M

Description

Application

3,5-Dimethylphenylmagnesium bromide solution can be used:

• As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.
• To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl₂ catalyst.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H302,H319,H335,H351
• pcodes: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -0.0 °F - closed cup
• flash_point_c: -17.78 °C - closed cup