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555967

Sigma-Aldrich

mono-Chloroborane dioxane complex

2.5 M in methylene chloride

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About This Item

Empirical Formula (Hill Notation):
C4H10BClO2
CAS Number:
Molecular Weight:
136.39
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:

reaction suitability

reagent type: reductant

concentration

2.5 M in methylene chloride

SMILES string

Cl[BH2-][O+]1CCOCC1

Application

Can readily substitute for common hydroborating reagents such as BH3 · THF and BMS.[1][2][3]

Legal Information

U.S. Pat. No. 6,008,414

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Josyula, K. V. B. et al
Tetrahedron Letters, 44, 7789-7789 (2003)
Kanth, J. V. B.; Brown, H. C.
Organic Letters, 1, 315-315 (1999)
J V Kanth et al.
The Journal of organic chemistry, 66(16), 5359-5365 (2001-08-04)
Several less volatile oxygen-containing Lewis bases, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and monoglyme, were examined as prospective mono- and dichloroborane carriers. Dioxane, ethyl acetate, and beta-chloroethyl ether form relatively stable boron trichloride adducts, but

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