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555134

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II)

97%

Synonym(s):

Co(dppf)Cl2, Dichloro[ferrocene-1,1′-diylbis(diphenylphosphine-P)]cobalt(II)

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About This Item

Linear Formula:
Cl2Co(P(C6H5)2C5H4)2Fe
CAS Number:
67292-36-8
Molecular Weight:
684.22
MDL number:
MFCD03427161
UNSPSC Code:
12161600
PubChem Substance ID:
24879173

assay

97%

form

solid

reaction suitability

core: cobalt
reagent type: catalyst

mp

224 °C (dec.) (lit.)

SMILES string

[Fe].Cl[Co]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Co.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;+2;/p-2

InChI key

GODCBYSHZAJJDR-UHFFFAOYSA-L

Application

Reactant for synthesis of homoleptic complexes of cobalt(0) and nickel(0)

Catalyst for Heck-type reactions of 6-halo-1-hexene derivatives

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

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