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531421

Sigma-Aldrich

Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate

Synonym(s):

Trimethylsilyl (fluorosulfonyl)difluoroacetate

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25 G
$209.00

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25 G
$209.00

About This Item

Linear Formula:
FSO2CF2CO2Si(CH3)3
CAS Number:
Molecular Weight:
250.27
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

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reaction suitability

reaction type: C-C Bond Formation

Quality Level

refractive index

n20/D 1.367 (lit.)

bp

156 °C (lit.)

density

1.27 g/mL at 25 °C (lit.)

functional group

fluoro

SMILES string

C[Si](C)(C)OC(=O)C(F)(F)S(F)(=O)=O

InChI

1S/C5H9F3O4SSi/c1-14(2,3)12-4(9)5(6,7)13(8,10)11/h1-3H3

InChI key

XHVSCKNABCCCAC-UHFFFAOYSA-N

Application

  • Fluoroalkylation agent

Reactant for:
  • Preparation of difluorocyclopropenes
  • Preparation of difluorocarbene reagents

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

80.1 °F - closed cup

flash_point_c

26.7 °C - closed cup


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Questions

  1. What is the maximum purity of TMSFS

    1 answer
    1. The minimum purity of this material is 90% as determined by GC. A review of recent lots shows a range of 92.2 - 97.1%.

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