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524670

Sigma-Aldrich

Luperox® DHD-9, 2-Butanone peroxide solution

~32 wt. % in phthalate-free plasticizer mixture

Synonym(s):

2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution

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About This Item

Linear Formula:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS Number:
Molecular Weight:
210.22
Beilstein/REAXYS Number:
1759757
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

reaction suitability

reagent type: oxidant

concentration

~32 wt. % in phthalate-free plasticizer mixture

refractive index

n20/D 1.437

density

0.99 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Application

Polymerization initiator

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Org. Perox. D - Repr. 2 - Skin Corr. 1B

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk_germany

WGK 1

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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J Chaudiere et al.
Neurotoxicology, 9(2), 173-179 (1988-01-01)
Rats fed a vitamin E-deficient diet from age 3-10 weeks were either maintained on a vitamin E-deficient diet or fed a vitamin E-enriched diet for 8 subsequent weeks. The content of vitamin E, endoperoxide-derived malonaldehyde, lipofluorescent material and polyunsaturated fatty
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
[An organic peroxide, methyl ethyl ketone peroxide, damage to cytochrome P-450 peroxidase and microsomal enzymes activity].
M Ando
Nihon eiseigaku zasshi. Japanese journal of hygiene, 41(2), 587-592 (1986-06-01)
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The

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