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520489

Sigma-Aldrich

3-Fluorophenylzinc iodide solution

0.5 M in THF

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About This Item

Linear Formula:
FC6H4ZnI
CAS Number:
Molecular Weight:
287.39
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

concentration

0.5 M in THF

density

0.995 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Fc1cccc([Zn]I)c1

InChI

1S/C6H4F.HI.Zn/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1

InChI key

GRDTUCMQMQTYBS-UHFFFAOYSA-M

Application

3-Fluorophenylzinc iodide can be used as a reagent to prepare arylvinyl indoles via thermolysis of phenyl substituted allenylphenyl azides.

Legal Information

Product of Rieke® Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup


Certificates of Analysis (COA)

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Allenyl azide cycloaddition chemistry. Synthesis of annelated indoles from 2-(allenyl) phenyl azide substrates
Feldman KS, et al.
Organic Letters, 8(14), 3113-3116 (2006)

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