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491047

Sigma-Aldrich

2-(Bromomethyl)pyridine hydrobromide

98%

Synonym(s):

(2-Pyridyl)methyl bromide hydrobromide, 2-Bromomethylpyridine monohydrobromide, 2-Picolyl bromide-hydrobromide

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$45.35
25 G
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About This Item

Empirical Formula (Hill Notation):
C6H6BrN · HBr
CAS Number:
31106-82-8
Molecular Weight:
252.93
MDL number:
MFCD01863544
UNSPSC Code:
12352100
PubChem Substance ID:
24872629
NACRES:
NA.22

$45.35

List Price$56.90Save 20%
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Available to ship onApril 22, 2025Details

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Quality Level

100

assay

98%

mp

149-152 °C (lit.)

functional group

bromo

SMILES string

Br[H].BrCc1ccccn1

InChI

1S/C6H6BrN.BrH/c7-5-6-3-1-2-4-8-6;/h1-4H,5H2;1H

InChI key

JQDNCGRNPYKRAO-UHFFFAOYSA-N

Related Categories

General description

2-(Bromomethyl)pyridine hydrobromide is a pyridine derivative. It participates in the synthesis of 7-nitrobenz-2-oxa-1,3-diazole (NBD) based colorimetric and fluorescence chemosensor.[1]

Application

2-(Bromomethyl)pyridine hydrobromide may be used in the preparation of :
  • 2-[1-(pyridin-2-ylmethyl)-1H-1,2,3-triazol-4-yl]pyridine[2]
  • 2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-one[3]
  • 8-methyl-2-morpholin-4-yl-7-(pyridin-2-ylmethoxy)-4H-1,3-benzoxazin-4-one[3]
  • trans-4-(4-(bis(pyridin-2-ylmethyl)amino)styryl)benzonitrile[4]
  • 2-[N-(2-aminoethanethiol) methyl]-pyridine[5]
  • 2-[N-(ethylenediamino)-methyl]-pyridine[5]
  • 3-(carboxymethyl)-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate[6]
  • 3-[(S)-1-carboxy-2-methylpropyl]-1-[(pyridin-2-yl)methyl]-3H-imidazol-1-ium trifluoroacetate[6]

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT0689
MKCJ6763
MKCB2254V
MKBR0169V
MKBL3851V

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A stilbene-based fluoroionophore for copper ion sensing in both reduced and oxidized environments.
Zhu MQ, et al.
Talanta, 81(1), 678-683 (2010)
Synthesis and characterization of platinum (II) complexes from trifluoromethyl phenylenediamine, picoline and N-benzyl ethylenediamine derivatives.
Almeida MVD, et al.
Journal of the Brazilian Chemical Society, 17(7), 1266-1273 (2006)
An NBD-based colorimetric and fluorescent chemosensor for Zn2+ and its use for detection of intracellular zinc ions.
Xu Z, et al.
Tetrahedron, 65(11), 2307-2312 (2009)
Green Catalysts: Solid-Phase Peptide Carbene Ligands in Aqueous Transition-Metal Catalysis.
Worm-Leonhard K and Meldal M.
European Journal of Organic Chemistry, 2008(31), 5244-5253 (2008)
Saleh Ihmaid et al.
European journal of medicinal chemistry, 45(11), 4934-4946 (2010-08-31)
A number of new 2-amino-[5, 6, 7 and 8]-O-substituted 1,3-benzoxazines, and 2-amino 8-methyl-7-O-substituted-1,3-benzoxazines were synthesized. Thirty one new compounds were tested for their effect on collagen induced platelet aggregation and it was found that the most active compounds were 8-methyl-2-morpholin-4-yl-7-(pyridin-3-ylmethoxy)-4H-1,3-benzoxazin-4-one
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