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480886

Sigma-Aldrich

Sodium borohydride

greener alternative

granular, 99.99% trace metals basis

Synonym(s):

Sodium tetrahydridoborate

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About This Item

Linear Formula:
NaBH4
CAS Number:
16940-66-2
Molecular Weight:
37.83
EC Number:
241-004-4
MDL number:
MFCD00003518
UNSPSC Code:
26111700
PubChem Substance ID:
24871724
NACRES:
NA.22

Quality Level

200

assay

99.99% trace metals basis

form

granular

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (dec.) (lit.)

greener alternative category

Enabling,

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Nanocrystalline superlattices in gold colloid solution have been prepared by ligand-induction using AuCl3 reduced with sodium borohydride. Nucleophilic addition of hydride ion from sodium borohydride is an inexpensive alternative method for the Baylis-Hillman reaction to form [E]-a-methylcinnamic acids. A reductant solution composed of NaBH4 and NaOH was used to form mercury cold vapor. NaBH4 may be used to generate hydrogen by catalytic hydrolysis.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV7435
MKCS9494
MKCQ3293
MKCN2654
MKCK9918

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Determination of Mercury in Fly Ash by Using Flow Injection Cold Vapor Isotope Dilution Inductively Coupled Plasma Mass Spectrometry.
Suh, Jung-Ki, et al.
Mass Spectrom., 3(2), 58-61 (2012)
Sandwich Enzyme--linked Immunosorbent Assay (ELISA) Analysis of Plant Cell Wall Glycan Connections.
Cornuault V and Knox JP
Bio-protocol, 4(8) (2014)
Metal Borohydrides as Hydrogen Storage Materials
Soloveichik GL
Material Matters, 2(2), 11-11 (2007)
Lin, X.M. et al.
Chemistry of Materials, 11, 198-198 (1999)
An effective nanosensor for organic molecules based on water-soluble mercaptopropionic acid-capped CdTe nanocrystals with potential application in high-throughput screening and high-resolution optical microscopy
Lau, Pick-Chung, et al.
Biomedical Optics Express, 5(7), 2420-2434 (2014)
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