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472255

Sigma-Aldrich

1,1,1-Trimethyl-N-(triphenylphosphoranylidene)silanamine

97%

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About This Item

Linear Formula:
(C6H5)3P=NSi(CH3)3
CAS Number:
Molecular Weight:
349.48
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

mp

76-82 °C (lit.)

functional group

phosphine

SMILES string

C[Si](C)(C)N=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C21H24NPSi/c1-24(2,3)22-23(19-13-7-4-8-14-19,20-15-9-5-10-16-20)21-17-11-6-12-18-21/h4-18H,1-3H3

InChI key

YTKOPFGRNPVCPE-UHFFFAOYSA-N

General description

1,1,1-Trimethyl-N-(triphenylphosphoranylidene)silanamine is an organic building block.

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Ranfeng Sun et al.
Organic & biomolecular chemistry, 12(31), 5954-5963 (2014-07-06)
A series of phosphinimine ligands were designed and used in the Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction of tetrazolo[1,5-a]pyridines and alkynes for the first time. By optimizing the reaction conditions, an efficient catalytic system (CuCl/2-PyCH2N[double bond, length as m-dash]P(t)Bu3) was developed

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