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470775

Sigma-Aldrich

Vanadium(V) oxytriethoxide

95%

Synonym(s):

Ethyl orthovanadate, Oxovanadium triethoxide, Tri(ethoxy)vanadium oxide, Triethoxyvanadyl, Triethyl vanadate, Vanadium oxytriethoxide

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About This Item

Linear Formula:
OV(OC2H5)3
CAS Number:
1686-22-2
Molecular Weight:
202.12
EC Number:
216-870-1
MDL number:
MFCD00799170
UNSPSC Code:
12352103
PubChem Substance ID:
24870679
NACRES:
NA.23

assay

95%

form

liquid

reaction suitability

core: vanadium
reagent type: catalyst

bp

125-128 °C (lit.)

density

1.139 g/mL at 25 °C (lit.)

SMILES string

CCO[V](=O)(OCC)OCC

InChI

1S/3C2H5O.O.V/c3*1-2-3;;/h3*2H2,1H3;;/q3*-1;;+3

InChI key

IOHMVQGDVUCILM-UHFFFAOYSA-N

Related Categories

Application

Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW6946
MKCJ4806
MKCF2832
MKBX4489V
MKBT7858V

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Feilong Jiang et al.
Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)
The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)

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