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Key Documents

468207

Sigma-Aldrich

Iron(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

Synonym(s):

Fe(TMHD)3

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About This Item

Linear Formula:
Fe[(CH3)3CCOCHCOC(CH3)3]
CAS Number:
Molecular Weight:
605.65
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

form

solid

reaction suitability

core: iron

mp

179-185 °C (lit.)

SMILES string

CC(C)(C)C(=O)\C=C(\O[Fe](O\C(=C\C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/3C11H20O2.Fe/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b2*8-7+;8-7-;

InChI key

NXBJVTQWYMSPSJ-GECNZSFWSA-K

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Application

Precursor for the formation of BaFe12O19 thin films on Al2O3 (0001) substrates in preferential orientation with the c-axis perpendicular to the substrate. Precursor for aerosol-assisted CVD of mixed-conducting ceramic films of Sr-Co-Fe perovskite phases.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Calvin D Pham et al.
ACS applied materials & interfaces, 9(42), 36980-36988 (2017-09-20)
A radical-enhanced atomic layer deposition (RE-ALD) process was developed for growing ferrimagnetic CoFe

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