446351

(S)-1-[(1-Methyl-2-pyrrolidinyl)methyl]piperidine

97%

• Synonym(s): (S)-1-Methyl-2-(piperidinomethyl)pyrrolidine
• Empirical Formula (Hill Notation): C₁₁H₂₂N₂
• CAS Number: 84466-85-3
• Molecular Weight: 182.31
• Beilstein/REAXYS Number: 4242955
• MDL number: MFCD18642280
• UNSPSC Code: 12352005
• PubChem Substance ID: 24868270
• NACRES: NA.22

Properties

• assay: 97%
• form: liquid
• optical activity: [α]20/D −69°, c = 0.5 in ethanol
• refractive index: n20/D 1.478 (lit.)
• bp: 121-123 °C/22 mmHg (lit.)
• density: 0.909 g/mL at 25 °C (lit.)
• SMILES string: CN1CCC[C@H]1CN2CCCCC2
• InChI: 1S/C11H22N2/c1-12-7-5-6-11(12)10-13-8-3-2-4-9-13/h11H,2-10H2,1H3/t11-/m0/s1
• InChI key: VCVPSRADUBPOKJ-NSHDSACASA-N

Description

Application

Useful chiral ligand for catalytic asymmetric aldol reactions. Mukaiyama, T.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 221.0 °F - closed cup
• flash_point_c: 105 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter