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Sigma-Aldrich

Tribromoacetyl chloride

97%

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About This Item

Linear Formula:
CBr3COCl
CAS Number:
34718-47-3
Molecular Weight:
315.19
MDL number:
MFCD00209618
UNSPSC Code:
12352100
PubChem Substance ID:
24867039
NACRES:
NA.22

vapor pressure

0.23 psi ( 20 °C)

assay

97%

form

liquid

refractive index

n20/D 1.583 (lit.)

density

1.628 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClC(=O)C(Br)(Br)Br

InChI

1S/C2Br3ClO/c3-2(4,5)1(6)7

InChI key

RDBMNMVDVKRYKW-UHFFFAOYSA-N

Application

Tribromoacetyl chloride may be used for the preparation of dihexadecyl N-(tribromoacetyl)-L-glutamate. It may be used for the synthesis of docetaxel.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Study of the Cine-Rearrangement and the Cinesubstitution of 2, 2-Dihalocyclobutanones.
Jose'Renato Cagnon JMB.
Journal of the Brazilian Chemical Society, 7(5), 371-377 (1996)
A novel two-dimensional photopolymerization at an oriented bilayer surface. Effective molecular-weight control using membrane state and chain transfer.
Higashi, N, et al.
Macromolecules, 23(5), 1475-1480 (1990)
Development of New Efficient Synthetic Methods for Docetaxel.
Heo JH, et al.
ChemInform, 40(29) (2009)
Cycloaddition of dihaloketenes with trimethylsiloxycycloolefins and fluorination of the products.
Habibi MH, et al.
Journal of Fluorine Chemistry, 37(2), 177-181 (1987)
Laser Raman and infrared spectra of tribromoacetyl-chloride.
Randhawa HS and Walter W.
Journal of Molecular Structure, 35(2), 303-307 (1976)

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