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Key Documents

422592

Sigma-Aldrich

Dilithium tetrabromonickelate(II) solution

0.5 M in THF

Synonym(s):

Lithium tetrabromonickelate(II) solution, di-Lithium tetrabromonickelate(II)

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About This Item

Linear Formula:
Li2NiBr4
CAS Number:
Molecular Weight:
392.19
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

form

liquid

reaction suitability

core: nickel
reagent type: catalyst

concentration

0.5 M in THF

bp

67 °C

density

1.065 g/mL at 25 °C

SMILES string

[Li+].[Li+].Br[Ni--](Br)(Br)Br

InChI

1S/4BrH.2Li.Ni/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

AVJDNPHXGKKFIA-UHFFFAOYSA-J

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Application

Catalyst for the regioselective preparation of magnetic resonance contrast agents

Reagent for:
  • Regioselective synthesis of (-)-gallocatechin
  • Synthesis of ATP mimics
  • Reaction with unsaturated epoxides

signalword

Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-0.4 °F - closed cup

flash_point_c

-18 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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