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417602

Sigma-Aldrich

2-Chloroethyl phenyl sulfide

98%

Synonym(s):

2-(Phenylthio)ethyl chloride

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About This Item

Linear Formula:
ClCH2CH2SC6H5
CAS Number:
5535-49-9
Molecular Weight:
172.68
Beilstein/REAXYS Number:
1907116
EC Number:
226-891-8
MDL number:
MFCD00013691
UNSPSC Code:
12352100
PubChem Substance ID:
24866164
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.583 (lit.)

bp

90-91 °C/1 mmHg (lit.)

density

1.174 g/mL at 25 °C (lit.)

functional group

chloro
thioether

SMILES string

ClCCSc1ccccc1

InChI

1S/C8H9ClS/c9-6-7-10-8-4-2-1-3-5-8/h1-5H,6-7H2

InChI key

QDXIHHOPZFCEAP-UHFFFAOYSA-N

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General description

2-Chloroethyl phenyl sulfide has been reported as sulfur mustard simulant. It is a chemical-warfare agent (CWA) simulant and its oxidation using hydrothane films has been reported. It is also reported as a simulant for the chemical warfare agent mustard [bis(2-chloroethyl) sulfide]. Its reaction with vesicular functionalized double-chain surfactant (potassium O, O′-didodecylphosphorodithioate) at pH 9.0 borate buffer affords [S-[(2-phenylthio)ethyl]O,O′-didodecylphosphorodithioate]. Its oxidation with H2O2 catalyzed by [MnL](ClO4)2 (L = N,N′,N″-tris(2-hydroxypropyl)-1,4,7-triazacyclononane) afforded 2-chloroethyl phenyl sulfone and phenyl vinyl sulfone.

Application

2-Chloroethyl phenyl sulfide, a sulfur mustard agent stimulant, may be used as target analyte in a bioassay for the detection of mustard agent.

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Carc. 1A - Eye Dam. 1 - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

219.2 °F - closed cup

flash_point_c

104 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
0000347367
0000347366
0000184557
0000193394
BGBC1750V

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Raymond T Gephart et al.
ACS applied materials & interfaces, 5(20), 10191-10200 (2013-09-26)
Using reactive singlet oxygen (1O2), the oxidation of chemical-warfare agent (CWA) simulants has been demonstrated. The zinc octaphenoxyphthalocyanine (ZnOPPc) complex was demonstrated to be an efficient photosensitizer for converting molecular oxygen (O2) to 1O2 using broad-spectrum light (450-800 nm) from
Fabiana Arduini et al.
Sensors (Basel, Switzerland), 15(2), 4353-4367 (2015-02-18)
In this work a novel bioassay for mustard agent detection was proposed. The bioassay is based on the capability of these compounds to inhibit the enzyme choline oxidase. The enzymatic activity, which is correlated to the mustard agents, was electrochemically
Reaction of a vesicular functionalized surfactant with 2-chloroethyl phenyl sulfide, a mustard simulant.
Jaeger DA, et al.
Langmuir, 15(21), 7180-7185 (1999)
Sulfide oxidation with H2O2 catalyzed by manganese complex of N,N',N?-tris(2-hydroxypropyl)-1, 4, 7-triazacyclononane.
Feng X-M, et al.
Inorgorganica Chimica Acta, 360(15), 4103-4110 (2007)
Quaternary ammonium O, O'-dialkylphosphorodithioate surfactants and their reactions with 2-chloroethyl phenyl sulfide, a mustard simulant.
Jaeger DA, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 196(2), 209-216 (2002)
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