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41409

Sigma-Aldrich

Ethoxydimethylphenylsilane

≥97.0% (GC)

Synonym(s):

Dimethylethoxyphenylsilane, Dimethylphenylethoxysilane

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About This Item

Empirical Formula (Hill Notation):
C10H16OSi
CAS Number:
Molecular Weight:
180.32
Beilstein/REAXYS Number:
2936696
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

assay

≥97.0% (GC)

refractive index

n20/D 1.479

bp

93 °C/25 mmHg (lit.)

density

0.924 g/mL at 20 °C (lit.)

SMILES string

CCO[Si](C)(C)c1ccccc1

InChI

1S/C10H16OSi/c1-4-11-12(2,3)10-8-6-5-7-9-10/h5-9H,4H2,1-3H3

Inchi Key

FIHCECZPYHVEJO-UHFFFAOYSA-N

General description

Ethoxydimethylphenylsilane undergoes trifluoroethanolysis in the presence of substituted acetic acids.{69}

Application

Ethoxydimethylphenylsilane can be used:
  • To functionalize SiO2 nanoparticles by the sol-gel method used in the bilayer coatings on a glass surface.
  • To functionalize the nanosized zeolites applicable in the catalysis.
  • As a substrate in the study of Si-O bond cleavage in the presence of serine hydrolases.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

156.2 °F - closed cup

flash_point_c

69 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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On the biocatalytic cleavage of silicon--oxygen bonds: A substrate structural approach to investigating the cleavage of protecting group silyl ethers by serine-triad hydrolases
Maraite A, et al.
Journal of Molecular Catalysis. B, Enzymatic, 56(1), 24-28 (2009)
The general acid catalyzed trifluoroethanolysis of ethoxydimethylphenylsilane
Dietze PE, et al.
Tetrahedron Letters, 32(3), 307-310 (1991)
Synthesis of aggregation-resistant MFI nanoparticles
Chen H, et al.
Catalysis Today (2019)
The influence of new hydrophobic silica nanoparticles on the surface properties of the films obtained from bilayer hybrids
Petcu C, et al.
Nanomaterials, 7(2), 47-47 (2017)

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