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411027

Sigma-Aldrich

Piperidine

≥99.5%, purified by redistillation

Synonym(s):

Hexahydropyridine

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About This Item

Empirical Formula (Hill Notation):
C5H11N
CAS Number:
110-89-4
Molecular Weight:
85.15
Beilstein/REAXYS Number:
102438
EC Number:
203-813-0
MDL number:
MFCD00005979
UNSPSC Code:
12352005
PubChem Substance ID:
24865722
NACRES:
NA.22

vapor density

3 (vs air)

Quality Level

200

vapor pressure

23 mmHg ( 20 °C)

assay

≥99.5%

form

liquid

purified by

redistillation

refractive index

n20/D 1.452 (lit.)

bp

106 °C (lit.)

mp

−13 °C (lit.)

density

0.862 g/mL at 20 °C (lit.)

SMILES string

C1CCNCC1

InChI

1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2

InChI key

NQRYJNQNLNOLGT-UHFFFAOYSA-N

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Application

Piperidine may be used as a base for the oxidative homocoupling of terminal alkynes to form symmetrical 1,4-disubstituted 1,3-diynes in the presence of copper nanoparticle on polyaniline support catalyst. It may also be used for cleaving the Fmoc-group in Nα-9-fluorenylmethyloxycarbonyl (Fmoc) amino acids.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR1345
SHBM2123
SHBM1506
SHBL2019
SHBJ9794

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