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Key Documents

409758

Sigma-Aldrich

N,N-Dimethyl-1,4-phenylenediamine oxalate

98%

Synonym(s):

N,N-Dimethyl-p-phenylenediamine hemioxalate salt

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About This Item

Linear Formula:
[(CH3)2NC6H4NH2]2·H2C2O4
CAS Number:
Molecular Weight:
362.42
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

powder

mp

205 °C (dec.) (lit.)

functional group

amine
carboxylic acid

SMILES string

OC(=O)C(O)=O.CN(C)c1ccc(N)cc1.CN(C)c2ccc(N)cc2

InChI

1S/2C8H12N2.C2H2O4/c2*1-10(2)8-5-3-7(9)4-6-8;3-1(4)2(5)6/h2*3-6H,9H2,1-2H3;(H,3,4)(H,5,6)

InChI key

MNUINXKPLPIOEF-UHFFFAOYSA-N

Application

N,N-Dimethyl-1,4-phenylenediamine oxalate (N,N-dimethyl-p-phenylenediamine hemioxalate salt, DPD) was used as reagent in a study to evaluate the catalytic effects of elemental sulfur nanoparticles on CrVI reduction. It was also used to study the transformation of trichloroethene (TCE), caused by heating contaminated soil and groundwater samples.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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On-line electrochemical-mass spectrometry study of the mechanism of oxidation of N, N-dimethyl-p-phenylenediamine in aqueous electrolytes.
Modestov AD, et al.
Journal of Electroanalytical Chemistry, 565(1), 7-19 (2004)
Jed Costanza et al.
Environmental science & technology, 43(3), 909-914 (2009-02-28)
This study explores the transformation of trichloroethene (TCE) caused by heating contaminated soil and groundwater samples obtained from the East Gate Disposal Yard (EGDY) located in Fort Lewis, WA. After field samples transferring into glass ampules and introducing 1.5 micromol
Yeqing Lan et al.
Environmental science & technology, 39(7), 2087-2094 (2005-05-06)
Chromate (CrVI) reduction by sulfide was conducted in anaerobic batch experimental systems. The molar ratio of the reduced CrVI to the oxidized S(-II) was 1:1.5 during the reaction, suggesting that the product of sulfide oxidation was elemental sulfur. Under the
F J Alcaín et al.
Redox report : communications in free radical research, 3(5-6), 287-293 (1998-12-16)
Swiss 3T3 fibroblasts can be weakly stimulated to grow by bombesin, epidermal growth factor or ceruloplasmin when cells are maintained in Dulbecco's Modified Essential Medium (DMEM), the pH of which is 7.75. Addition of insulin synergizes with the other mitogens.
Claudineia R Silva et al.
Talanta, 85(3), 1703-1705 (2011-08-03)
A spectrophotometric flow injection procedure involving N,N-dimethyl-p-phenylenediamine (DMPD) is applied to the sulfide monitoring of a sugar fermentation by Saccharomyces cerevisiae under laboratory conditions. The gaseous chemical species evolving from the fermentative process, mainly CO(2), are trapped allowing a cleaned

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