Skip to Content
MilliporeSigma
All Photos(1)

Documents

398845

Sigma-Aldrich

Lead(IV) acetate

≥99.99% trace metals basis

Synonym(s):

Lead tetraacetate, Pb(acac)4

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
Pb(CH3CO2)4
CAS Number:
546-67-8
Molecular Weight:
443.38
Beilstein/REAXYS Number:
3595640
EC Number:
208-908-0
MDL number:
MFCD00008693
UNSPSC Code:
12352300
PubChem Substance ID:
24864770

assay

≥99.99% trace metals basis

reaction suitability

core: lead
reagent type: catalyst

SMILES string

CC(=O)O[Pb](OC(C)=O)(OC(C)=O)OC(C)=O

InChI

1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4

InChI key

JEHCHYAKAXDFKV-UHFFFAOYSA-J

Looking for similar products? Visit Product Comparison Guide

Application

Smoothly induces the addition of difluorodiiodomethane to alkenes and alkynes.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Li, A-R. Chen, Q-Y.
Synthesis, 1481-1481 (1997)
Hidehito Urata et al.
Chemical & pharmaceutical bulletin, 56(11), 1611-1612 (2008-11-05)
The first chemical synthesis of two metabolites ((1R,2S,5R,6S)-6-(3,4-dihydroxyphenyl)-2-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-1) and (1R,2S,5R,6S)-2,6-bis(3,4-dihydroxyphenyl)-3,7-dioxabicyclo[3,3,0]octane (SC-2)) of sesamin was achieved by a simple two-step approach from sesamin. The approach consists of acetoxylation of the methylenedioxy moiety(ies) with lead(IV) tetraacetate and acid hydrolysis of the
H Mallesha et al.
Nucleosides, nucleotides & nucleic acids, 21(4-5), 385-392 (2002-08-17)
Lead tetraacetate (LTA) oxidation of alpha-Phenyl-N-(4-bipheny])nitrone (8) to give a new ultimate carcinogen, N-acetoxy-N-benzoyl-4-aminobiphenyl (9) which was reacted with deoxyguanosine (dG) at pH 6.9 to give nucleoside derivative, N-(benzoyl)-N-(deoxyguanosin-8-yl)-4-aminobiphenyl (10). Following debenzoylation with sodium carbonate-methanol leads to N-(2'-deoxyguanosin-8-yl)-4-aminobiphenyl (11).
W Banner et al.
Toxicology and applied pharmacology, 83(1), 142-147 (1986-03-30)
The usefulness of N-acetylcysteine (NAC) as a chelating agent was studied for the toxin potassium dichromate, lead tetraacetate, and boric acid. Mature Sprague-Dawley rats were intoxicated with these substances and placed in metabolic cages. Urinary excretion rates of intoxicant and
N S Kumar et al.
Carbohydrate research, 291, 109-114 (1996-09-23)
Oxidative decarboxylation of peracetylated welan gum (S-130) with lead tetraacetate resulted in selective cleavage of the glucuronosidic linkages. Products of the degradation were reduced with sodium borohydride, O-deacetylated, and fractionated. Polymeric and oligomeric fractions were separated and analysed by 1H
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service