393290
Tris(dimethylamino)phosphine
97%
Synonym(s):
(Me2N)3P, Hexamethyltriamidophosphite, Hexamethyltriaminophosphine, HMPT, Hexamethylphosphorous triamide
About This Item
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Quality Level
assay
97%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Reductions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Wittig Reaction
refractive index
n20/D 1.463 (lit.)
bp
48-50 °C/12 mmHg (lit.)
density
0.898 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CN(C)P(N(C)C)N(C)C
InChI
1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
InChI key
XVDBWWRIXBMVJV-UHFFFAOYSA-N
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Application
- Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
- Phosphorus source along with InCl3 in the synthesis of InP colloidal quantum dots (QDs).
- Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C60.
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Skin Irrit. 2
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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