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376035

Sigma-Aldrich

(Ethylthio)trimethylsilane

technical grade, 90%

Synonym(s):

Ethyl trimethylsilyl sulfide, Trimethylsilyl ethyl sulfide

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About This Item

Linear Formula:
C2H5SSi(CH3)3
CAS Number:
Molecular Weight:
134.32
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

90%

form

liquid

refractive index

n20/D 1.45 (lit.)

bp

69-70 °C/100 mmHg (lit.)

density

0.83 g/mL at 25 °C (lit.)

SMILES string

CCS[Si](C)(C)C

InChI

1S/C5H14SSi/c1-5-6-7(2,3)4/h5H2,1-4H3

InChI key

HXAFQWICVBBXMZ-UHFFFAOYSA-N

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General description

(Ethylthio)trimethylsilane is reported to participate in the synthesis of adenophostin A and analog. It reacts with primary and secondary amines to yield aminosilane and ethanethiol.

pictograms

Flame

signalword

Danger

hcodes

pcodes

Hazard Classifications

Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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An expeditious route to the synthesis of adenophostin A.
van Straten NCR, et al.
Tetrahedron, 53(18), 6509-6522 (1997)
Some reactions of silyl-and germyl-sulphur compound with the S< sup> II</sup>? N bond.
Armitage DA and Clark MJ.
Journal of Organometallic Chemistry, 24(3), 629-631 (1970)

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