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Key Documents

375993

Sigma-Aldrich

Dimethyl trimethylsilylmethylphosphonate

97%

Synonym(s):

[(Trimethylsilyl)methyl]-phosphonic acid dimethyl ester

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About This Item

Linear Formula:
(CH3)3SiCH2P(O)(OCH3)2
CAS Number:
Molecular Weight:
196.26
Beilstein/REAXYS Number:
2412153
MDL number:
UNSPSC Code:
12352000

assay

97%

refractive index

n20/D 1.435 (lit.)

bp

111-114 °C/21.5 mmHg (lit.)

density

1.024 g/mL at 25 °C (lit.)

SMILES string

COP(=O)(C[Si](C)(C)C)OC

InChI

1S/C6H17O3PSi/c1-8-10(7,9-2)6-11(3,4)5/h6H2,1-5H3

InChI key

QBHFBIHXALNDCB-UHFFFAOYSA-N

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Application

Reactant for:
  • Synthesis of phosphonato-phosphine palladacycles
  • Studying the synthetic applications of phosphoryl-stabilized anions
  • Peterson olefination reactions
  • Dilithiation and transmetalation

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