369268

α-Methylferrocenemethanol

97%

• Synonym(s): 1-(Ferrocenyl)ethanol, α-Ferrocenylethanol, α-Methylferrocenemethanol, (1-Hydroxyethyl)ferrocene, NSC 162110
• Empirical Formula (Hill Notation): C₁₂H₁₄FeO
• CAS Number: 1277-49-2
• Molecular Weight: 230.08
• MDL number: MFCD00013752
• UNSPSC Code: 12352300
• PubChem Substance ID: 24862812

Properties

• assay: 97%
• reaction suitability: core: iron; reagent type: catalyst
• mp: 76-79 °C (lit.)
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.CC(O)[C]2[CH][CH][CH][CH]2
• InChI: 1S/C7H9O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-6,8H,1H3;1-5H;
• InChI key: NJPGTUIMEAOISI-UHFFFAOYSA-N

Description

Application

• Ligand in titanium-catalyzed intermolecular hydroamination of terminal alkynes (Markovnikov vs. anti-Markovnikov addition)

Reactant for:

• Single-electron transfer living radical polymerization reactions
• Preparation of ferrocene-modified thiopyrimidines as anticancer agents
• Preparation of rersible addition-fragmentation chain transfer (RAFT) agent for RAFT polymerization of styrene

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves