360155

Bis(salicylideniminato-3-propyl)methylaminocobalt(II)

97%

• Synonym(s): [[α,α′-[(Methylimino)bis(trimethylenenitrilo)]di-o-cresolato](2-)]cobalt, [[2,2′-[(Methylimino-κN)bis[3,1-propanediyl(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]cobalt
• Linear Formula: CH₃N[(CH₂)₃N=CHC₆H₄-2-(O)]₂Co
• CAS Number: 15391-24-9
• Molecular Weight: 410.38
• MDL number: MFCD00134174
• UNSPSC Code: 12352300
• PubChem Substance ID: 24862151
• NACRES: NA.22

Properties

• assay: 97%
• reaction suitability: core: cobalt; reagent type: catalyst
• mp: 290-292 °C (lit.)
• SMILES string: CN1CCC\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\CCC1
• InChI: 1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;/q;+2/p-2/b22-16+,23-17+;
• InChI key: BJSFADUIUGJFKX-VLQAMQNLSA-L

Description

Application

Catalyst for:

• Biomimetic coupled catalytic system
• Cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics
• Allylation, oxidation, and oxidative cleavages
• Oxidative carbonylation of phenol

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332,H315,H319,H335
• pcodes: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves