358002

(3aR)-(+)-Sclareolide

97%

• Synonym(s): (+)-Norambreinolide
• Empirical Formula (Hill Notation): C₁₆H₂₆O₂
• CAS Number: 564-20-5
• Molecular Weight: 250.38
• EC Number: 209-269-0
• MDL number: MFCD00134168
• UNSPSC Code: 12352005
• PubChem Substance ID: 24861957
• NACRES: NA.22

Properties

• assay: 97%
• form: powder
• optical activity: [α]20/D +47°, c = 2% in chloroform
• mp: 124-126 °C (lit.)
• functional group: ester
• SMILES string: [H][C@@]12CC[C@@]3(C)OC(=O)C[C@]3([H])[C@@]1(C)CCCC2(C)C
• InChI: 1S/C16H26O2/c1-14(2)7-5-8-15(3)11(14)6-9-16(4)12(15)10-13(17)18-16/h11-12H,5-10H2,1-4H3/t11-,12+,15-,16+/m0/s1
• InChI key: IMKJGXCIJJXALX-SHUKQUCYSA-N

Description

General description

Sclareolide is a diterpenoid compound mainly used in the perfume industry for its amber like odor.

Application

(3aR)-(+)-Sclareolide may be used in the total syntheses of bioactive compounds such as (+)-chloropuupehenone, (+)-chloropuupehenol, cyslabdan, acuminolide and 17-O-acetylacuminolide. It may also be used in the preparation of γ-bicyclohomofarnesal, an ambergris odorant.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)