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35170

Sigma-Aldrich

2,4-Dichloroaniline

≥97.0% (GC)

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About This Item

Linear Formula:
Cl2C6H3NH2
CAS Number:
Molecular Weight:
162.02
Beilstein/REAXYS Number:
386422
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

≥97.0% (GC)

bp

245 °C (lit.)

mp

59-62 °C (lit.)
60-65 °C

solubility

methanol: soluble, clear, very faintly brownish-yellow

SMILES string

Nc1ccc(Cl)cc1Cl

InChI

1S/C6H5Cl2N/c7-4-1-2-6(9)5(8)3-4/h1-3H,9H2

InChI key

KQCMTOWTPBNWDB-UHFFFAOYSA-N

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General description

2,4-Dichloroaniline is an organic xenobiotic compound and its acute toxicity, modes of action and physicochemical properties towards the freshwater crustacean amphipod Gammarus pulex has been investigated. Biodegradation of 2,4-dichloroaniline by new strain Delftia tsuruhatensis H1 has been reported. The electrochemical oxidation of 2,4-dichloroaniline was studied in acetonitrile solution. Quantitative method for the detection of 2,4-dichloroaniline in environmental water samples by solid-phase microextraction (SPME) in gas chromatography–mass spectrometry has been reported.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

239.0 °F - closed cup

flash_point_c

115 °C - closed cup


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The electrochemical oxidation of 4-chloroaniline, 2, 4-dichloroaniline and 2, 4, 6-trichloroaniline in acetonitrile solution.
Kadar M, et al.
Electrochimica Acta, 46(9), 1297-1306 (2001)
Determination of aromatic amines by solid-phase microextraction and gas chromatography−mass spectrometry in water samples.
Muller L, et al.
Journal of Chromatography A, 791(1), 221-230 (1997)
Phototransformation of 2,4-dichloroaniline in a surface freshwater environment: effects on microbial assemblages.
H M Hwang et al.
Bulletin of environmental contamination and toxicology, 60(1), 81-87 (1998-03-04)
Sophie Pascal-Lorber et al.
Journal of agricultural and food chemistry, 51(16), 4712-4718 (2004-01-07)
The uptake and metabolism of [14C]-2,4-dichlorophenol (DCP) and [14C]-2,4-dichloroaniline (DCA) were investigated in wheat and soybean. Seeds were exposed to a nutrient solution containing 50 microM of one of two radiolabeled compounds, and plant organs were harvested separately after 18
Michael Kilemade et al.
Aquatic toxicology (Amsterdam, Netherlands), 63(3), 207-219 (2003-04-25)
Interest in and concern for the quality of the environment has prompted a great deal of research into methods of measuring and assessing changes in it. One problem of major interest is that of increasing amounts of mutagenic/carcinogenic chemicals generated

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