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346462

Sigma-Aldrich

Zirconium(IV) oxynitrate hydrate

technical grade

Synonym(s):

Zirconyl nitrate hydrate

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100 G
$115.00
500 G
$404.00

About This Item

Linear Formula:
ZrO(NO3)2 · xH2O
CAS Number:
Molecular Weight:
231.23 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
grade:
technical grade
form:
powder

$115.00


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grade

technical grade

Quality Level

form

powder

composition

Degree of hydration, ~6

concentration

25-30% Zr (after ignition to oxide, gravimetric)

application(s)

battery manufacturing

SMILES string

O=[Zr++].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*-1;;;+2

InChI key

BGMQNYCWALSARE-UHFFFAOYSA-N

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General description

Zirconium(IV) oxynitrate hydrate is an inorganic salt primarily used as a precursor for the synthesis of zirconium nanoparticles, to fabricate Li-ion batteries, and as a catalyst in various chemical reactions.[1] [2]

Application

Zirconium(IV) oxynitrate hydrate can be used:
  • As a starting material to prepare electrolytes for Li-ion batteries.[1]
  • For the surface modification of cathodes, to enhance the electrochemical properties of all-solid-state batteries.[3]
  • As a precursor for surfactant-free synthesis of zirconia nanostructures.[4]
It can also be used as a catalyst for:
  • Regiospecific alcoholysis and aminolysis of epoxides.[2]
  • One-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores.[5]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

supp_hazards

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Enhanced electrochemical properties of all-solid-state batteries using a surface-modified LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode
Chung Bum Lim, et al.
Journal of Electrochemical Science and Technology, 11, 411-420 (2020)
Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate
Sandip S. Shinde, et al.
Tetrahedron Letters, 56, 5916-5919 (2015)
Zirconia Nanostructures: Novel Facile Surfactant-Free Preparation and Characterization
Sahar Zinatloo-Ajabshir, et al.
International Journal of Applied Ceramic Technology, 13, 108-115 (2016)
Zirconium(IV)-catalyzed one-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores as new pH indicators or calorimetric chemosensors for transition metals
Alireza Khorshidi, et al.
Tetrahedron Letters, 55, 3873-3877 (2014)
The Structure and Electrical Properties of Li7La3Zr1.0Sn1.0O12 as Electrolyte Material for Li-ion Batteries
Siti Nur Adlina Norazman, et al.
Advances in Science and Technology, 118, 27-32 (2022)

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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