345229

Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)

99%

• Synonym(s): NSC 241246, Tetramethylethylenediaminepalladium dichloride, [1,2-Bis(dimethylamino)ethane]dichloropalladium
• Linear Formula: [(CH₃)₂NCH₂CH₂N(CH₃)₂]PdCl₂
• CAS Number: 14267-08-4
• Molecular Weight: 293.53
• MDL number: MFCD00075317
• UNSPSC Code: 12352300
• PubChem Substance ID: 24861301

Properties

• assay: 99%
• form: powder
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 245 °C (dec.) (lit.)
• SMILES string: Cl[Pd]Cl.CN(C)CCN(C)C
• InChI: 1S/C6H16N2.2ClH.Pd/c1-7(2)5-6-8(3)4;;;/h5-6H2,1-4H3;2*1H;/q;;;+2/p-2
• InChI key: FJOUSQLMIDWVAY-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Cross-coupling reactions
• Catalytic reduction reactions
• Preparation of silyl ethers via reaction of silicon-hydrogen bond with alcohols
• Oxidative carbonylation reactions

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves