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337501

Sigma-Aldrich

[Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(I) hexafluorophosphate

97%

Synonym(s):

[(2,3-η)-Bicyclo[2.2.1]hepta-2,5-diene]tris(dimethylphenylphosphine)rhodium(I) hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C31H41F6P4Rh
CAS Number:
Molecular Weight:
754.45
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

assay

97%

reaction suitability

core: rhodium
reagent type: catalyst

mp

158-161 °C (lit.)

SMILES string

[Rh+].F[P-](F)(F)(F)(F)F.[CH]1[CH]C2[CH][CH]C1C2.CP(C)c3ccccc3.CP(C)c4ccccc4.CP(C)c5ccccc5

InChI

1S/3C8H11P.C7H8.F6P.Rh/c3*1-9(2)8-6-4-3-5-7-8;1-2-7-4-3-6(1)5-7;1-7(2,3,4,5)6;/h3*3-7H,1-2H3;1-4,6-7H,5H2;;/q;;;;-1;+1

InChI key

KSBHDOZWEREXLG-UHFFFAOYSA-N

Application

Catalyst for aminomethylation

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Gaspard Huber et al.
Magnetic resonance in chemistry : MRC, 56(7), 672-678 (2017-12-09)
Cryptophanes, cage-molecules constituted of aromatic bowls, are now well recognised as powerful xenon hosts in 129 Xe NMR-based biosensing. In the quest of a dual probe that can be addressed only by NMR, we have studied three cryptophanes bearing a

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