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328332

Sigma-Aldrich

Dimethylphosphinic chloride

97%

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About This Item

Linear Formula:
(CH3)2P(O)Cl
CAS Number:
Molecular Weight:
112.50
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

bp

204 °C (lit.)

mp

65-71 °C (lit.)

functional group

phosphine oxide

SMILES string

CP(C)(Cl)=O

InChI

1S/C2H6ClOP/c1-5(2,3)4/h1-2H3

InChI key

CVNMBKFJYRAHPO-UHFFFAOYSA-N

General description

Kinetics of pyridinolyses of dimethylphosphinic chloride in acetonitrile was studied. Kinetics and mechanism of the reaction of dimethyl phosphinic chloride with anilines in acetonitrile was studied.

Application

Dimethylphosphinic chloride was used in preparation of dimethyl-ethynylphosphine oxide.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Dialkylethynylphosphine oxides; synthesis and reactions.
Hagens W, et al.
Rec. Trav. Chim., 88(1), 71-85 (1969)
Kinetics and mechanism of the aminolysis of dimethyl and methyl phenyl phosphinic chlorides with anilines.
Dey NK, et al.
Journal of Physical Organic Chemistry, 22(5), 425-430 (2009)
Pyridinolysis of Diethyl Phosphinic Chloride in Acetonitrile.
Dey NK, et al.
Bull. Korean Chem. Soc., 32(2), 709-712 (2011)

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