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328294

Sigma-Aldrich

Dimethylphosphinic acid

97%

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About This Item

Linear Formula:
(CH3)2P(O)OH
CAS Number:
Molecular Weight:
94.05
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

mp

85-89 °C (lit.)

SMILES string

CP(C)(O)=O

InChI

1S/C2H7O2P/c1-5(2,3)4/h1-2H3,(H,3,4)

InChI key

GOJNABIZVJCYFL-UHFFFAOYSA-N

Related Categories

General description

Infrared spectra for gaseous and polycrystalline samples of dimethylphosphinic acid at various temperatures are reported. The molecular structure of the hydrogen bonded cyclic dimer of dimethylphosphinic acid was studied by gas-phase electron diffraction at 433K.

Application

Dimethylphosphinic acid was used in preparation of microcrystalline organometallic coordination polymer.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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First example of the ABC ? (OH) absorption structure for both gaseous and crystalline phase: infrared studies of dimethylphosphinic acid.
Tokhadze KG, et al.
Journal of Molecular Structure, 404(1), 55-62 (1997)
Gas-phase electron diffraction study of cyclic dimer of dimethylphosphinic acid (Me< sub> 2</sub> P (? O) OH)< sub> 2</sub> using quantum chemical data and a priori force field.
Khaikin LS, et al.
Journal of Molecular Structure, 658(3), 153-170 (2003)
Christopher M. Barnes et al.
Inorganic chemistry, 36(25), 5793-5798 (2001-10-24)
The microcrystalline organometallic coordination polymer [Ru(2){&mgr;(2):&mgr;(2):eta(2)-O(2)PMe(2)}(2)(CO)(4)](n)() which results from the oxidative addition of dimethylphosphinic acid to triruthenium dodecacarbonyl has been structurally characterized by X-ray powder diffraction, lambda = 1.149 49(1) Å, at 295 and 50 K. At room temperature the

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