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Sigma-Aldrich

Phenyl vinylsulfonate

95%

Synonym(s):

Phenyl ethylenesulfonate, Vinylsulfonic acid phenyl ester

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About This Item

Linear Formula:
CH2=CHSO3C6H5
CAS Number:
1562-34-1
Molecular Weight:
184.21
Beilstein/REAXYS Number:
2044718
MDL number:
MFCD00012206
UNSPSC Code:
12352100
PubChem Substance ID:
24858413
NACRES:
NA.22

assay

95%

bp

44-46 °C/2 mmHg (lit.)

mp

38-42 °C (lit.)

SMILES string

C=CS(=O)(=O)Oc1ccccc1

InChI

1S/C8H8O3S/c1-2-12(9,10)11-8-6-4-3-5-7-8/h2-7H,1H2

InChI key

CILDJVVXNMDAGY-UHFFFAOYSA-N

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General description

Phenyl vinylsulfonate is an ester. Palladium complex derived from a tetraphosphine-catalyzed Heck vinylation of phenyl vinylsulfonate was reported.[1] Phenyl vinyl sulfonate reacts with various alkyl furan derivatives to yield the corresponding cycloadducts.[2]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
35797LJV
35797LJ
08331MH
04202EH
09614CD

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Mild and practical cycloaddition reactions of furans with phenyl vinyl sulfonate.
Klein LL and Deeb TM.
Tetrahedron Letters, 26(33), 3935-3938 (1985)
Heck vinylations using vinyl sulfide, vinyl sulfoxide, vinyl sulfone, or vinyl sulfonate derivatives and aryl bromides catalyzed by a palladium complex derived from a tetraphosphine.
Battace A, et al.
Synthesis, 2006(20), 3495-3505 (2006)

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