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301612

Sigma-Aldrich

9-Anthraldehyde oxime, predominantly syn

99%

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About This Item

Empirical Formula (Hill Notation):
C15H11NO
CAS Number:
34810-13-4
Molecular Weight:
221.25
MDL number:
MFCD00012252
UNSPSC Code:
12352100
PubChem Substance ID:
24858201
NACRES:
NA.22

assay

99%

mp

162-164 °C (lit.)

SMILES string

O\N=C\c1c2ccccc2cc3ccccc13

InChI

1S/C15H11NO/c17-16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10,17H/b16-10+

InChI key

HLGMTCSSRBPNOQ-MHWRWJLKSA-N

General description

Gallium triflate catalyzed dehydration of 9-anthraldehyde oxime to nitrile is reported.

Application

9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)].

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Synthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligand derived from 9-anthraldehyde oxime.
Wong JS-Y, et al.
Inorganic Chemistry Communications, 6(6), 713-717 (2003)
Gallium (III) triflate catalyzed dehydration of aldoximes.
Yan P, et al.
Catalysis Letters, 101(3), 141-143 (2005)

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