294071
Methoxymethyl phenyl sulfide
97%
Synonym(s):
[(Methoxymethyl)thio]benzene
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About This Item
Linear Formula:
C6H5SCH2OCH3
CAS Number:
Molecular Weight:
154.23
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
assay
97%
refractive index
n20/D 1.5632 (lit.)
bp
113-114 °C/18 mmHg (lit.)
density
1.047 g/mL at 25 °C (lit.)
functional group
ether
thioether
SMILES string
COCSc1ccccc1
InChI
1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3
InChI key
QPXQVNXSQCRWEV-UHFFFAOYSA-N
General description
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.
Application
Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
203.0 °F - closed cup
flash_point_c
95 °C - closed cup
ppe
Eyeshields, Gloves
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Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.
Maricich TJ and Harrington CK.
Journal of the American Chemical Society, 94(14), 5115-5116 (1972)
Solvent free permanganate oxidations.
Shaabani A and Lee DG.
Tetrahedron Letters, 42(34), 5833-5836 (2001)
S P Hanlon et al.
Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)
The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic
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